Nickel metal hydride battery

From EVProduction
Jump to: navigation, search

A nickel metal hydride battery, abbreviated NiMH, is a type of rechargeable battery similar to a nickel-cadmium (NiCd) battery but has a hydrogen-absorbing alloy for the anode instead of cadmium. Like in NiCd batteries, nickel is the cathode. A NiMH battery can have two to three times the capacity of an equivalent size NiCd and the memory effect is not as significant. However, compared to the lithium-ion battery, the volumetric energy density is lower and self-discharge is higher.

Applications of NiMH type batteries includes hybrid vehicles such as the Toyota Prius and consumer electronics. The NiMH technology will also be used on the Alstom Citadis low floor tram ordered for Nice, France; as well as the humanoid prototype robot ASIMO designed by Honda. Standard NiMH batteries perform better with moderate drain devices such as digital cameras, flashlights, and other consumer electronics. Because NiCd batteries have lower internal resistance, they still have the edge in very high current drain applications such as cordless power tools and RC cars.

Charging

File:Charge NiMH.svg
NIMH Charge curve

The charging voltage is 1.4-1.6 V/cell.[1] Duracell recommends "a maintenance charge of indefinite duration at C/300 rate". A fully charged cell measures 1.35-1.4 V (unloaded), and supplies a nominal average 1.2V during discharge, down to about 1.0V (further discharge may cause permanent damage). Voltage Depression ("Memory Effect") from repeated partial discharge can occur, but is reversible through charge cycling. [2]

When fast-charging, it is advisable to charge the NiMH batteries with a smart battery charger to avoid overcharging, which can damage batteries and cause dangerous conditions. Modern NiMH batteries contain catalysts to immediately deal with gases developed as a result of over-charging without being harmed (2 H2 + O2 ---catalyst--> 2 H2O). However, this only works with over-charging currents of up to C/10 h (nominal capacity divided by 10 hours). As a result of this reaction, the batteries will heat up considerably, marking the end of the charging process. Some quick chargers have a fan to keep the batteries cool.

Some equipment manufacturers consider that NiMH can be safely charged in simple fixed (low) current chargers with or without timers, and that permanent over-charging is permissible with currents up to C/10 h. In fact, this is what happens in cheap cordless phone base stations and the cheapest battery chargers. Although this may be safe, it may not be good for the health of the battery. According to the Panasonic NiMH charging manual (link below), permanent trickle charging (small current overcharging) can cause battery deterioration and the trickle charge rate should be limited to between 0.033×C per hour and 0.05×C per hour for a maximum of 20 hours to avoid damaging the batteries.

Long-term maintenance charge of NiMH batteries needs to be by low duty cycle pulses of high current rather than continuous low current in order to preserve battery health.

Brand new batteries, or batteries which have been unused for some time, need "reforming" to reach their full capacity. For this reason new batteries may need several charge/discharge cycles before they operate to their advertised capacity.

Discharging

Care must also be taken during discharge to ensure that one or more cells in a series-connected battery pack, like the common arrangement of four AA cells in series in a digital camera, do not become completely discharged and go into polarity reversal. Cells are never absolutely identical, and inevitably one will be completely discharged before the others. When this happens, the "good" cells will start to "drive" the discharged cell in reverse, which can cause permanent damage to that cell. Some cameras, GPS receivers and PDAs detect the safe end-of-discharge voltage of the series cells and shut themselves down, but devices like flashlights and some toys do not. Once noticeable dimming or slowing of the device is noticed, it should be turned off immediately to avoid polarity reversal. A single cell driving a load won't suffer from polarity reversal, because there are no other cells to reverse-charge it when it becomes discharged.

NiMH chemistry has a somewhat higher self-discharge rate than the NiCd chemistry. The self-discharge is 5-10% on the first dayTemplate:Fact, and stabilizes around 0.5-1% per day at room temperature. The rate is strongly affected by the temperature at which the batteries are stored with cooler storage temperatures leading to slower discharge rate and longer battery life. The highest capacity cells on the market (> 2300mAh) are reported to have the highest discharge rates.

Low Self Discharge Batteries

A new type of nickel metal hydride battery was introduced in 2006 that claims to reduce self discharge, and therefore lengthen shelf life. By using a new separator, manufacturers claim between 70 to 85% of capacity is retained after one year, when stored at 20 degrees Celsius (68F). These cells are marketed as "ready to use" rechargeables, and are targeted towards typical consumers who use their digital cameras only a few times a year. Besides the longer shelf life, they are otherwise similar to normal NiMH batteries of equivalent capacity, and can be charged in typical NiMH chargers. Some brands that are currently available on the market (May 2007) are Accupower Acculoop, Ansmann MaxE range, Gold Peak ReCyko, Kodak Pre Charged, Nexcell EnergyOn, Panasonic R2, Rayovac Hybrid, Sanyo Eneloop, Titanium Power Enduro, Uniross Hybrio, and VARTA Ready2use. These appear to be available in AA and AAA sizes only, and have less capacity (2000~2100mAh in AA) than the current generation of high capacity cells (2800mAh, AA).

History and other information

File:NiMH 2500mAh.jpg
Modern, high capacity NiMH rechargeable batteries

NiMH battery technology was developed at the end of the 1980's and commercialised first by the Matsushita Company Template:Fact.

see discussion in "History..." on earlier invention and pioneering development (1964) and patent application filed in 1967.



Common penlight-size (AA) batteries have nominal capacities C ranging from 1100 mA·h to 2700 mA·h at 1.2 V, usually rated at 0.2×C rate. Useful discharge capacity is an inverse function of the discharge rate, but up to around 1×C rate, there is no significant difference. NiMH batteries have an alkaline electrolyte, usually potassium hydroxide. The specific energy density for NiMH material is approximately 70 W·h/kg (250 kJ/kg), with a volumetric energy density of about 300 W·h/L (360 MJ/m³).

Sometimes, voltage-sensitive devices won't perform well because the voltage is lower than disposable batteries at equivalent sizes. Even though the voltage is lower, it can be beneficial for the length of the discharge cycle.

Cadmium is poisonous, so NiMH batteries are less detrimental to the environment than NiCd batteries. Battery recycling programs exist to take care of end-of-life batteries.

Chemistry

The anode reaction occurring in a NiMH battery is as follows: H2O + Mm + e ↔ OH + Mm-H The battery is charged in the right direction of this equation and discharged in the left direction. Nickel(II) hydroxide forms the cathode.

The "metal" in a NiMH battery is actually an intermetallic compound. Many different compounds have been developed for this application, but those in current use fall into two classes. The most common is AB5, where A is a rare earth mixture of lanthanum, cerium, neodymium, praseodymium and B is nickel, cobalt, manganese, and/or aluminum. Very few batteries use higher-capacity negative material electrodes based on AB2 compounds, where A is titanium and/or vanadium and B is zirconium or nickel, modified with chromium, cobalt, iron, and/or manganese, due to the reduced life performances [3].

Any of these compounds serves the same role, reversibly forming a mixture of metal hydride compounds. When hydrogen ions are forced out of the potassium hydroxide electrolyte solution by the voltage applied during charging, this process prevents them from forming a gas, allowing a low pressure and volume to be maintained. As the battery is discharged, these same ions are released to participate in the reverse reaction.

Advantages vs. Alkaline

NiMH batteries and chargers are readily available in retail stores in common sizes: AAA, AA, C and D. They are not expensive, and the voltage and performance is similar to standard Alkaline batteries in those sizes; they can be substituted for most purposes -- digital cameras are a particularly good use. The ability to recharge hundreds of times can save a lot of money and resources. Unlike NiCd rechargable batteries, NiMH do not contain heavy metals, or other materials of special concern. The drawback of NiMH is that they lose about 1% of their charge per day. This is not a problem in the short term, but makes them unsuitable for many light-duty uses, such as clocks, remote controls or safety devices, where the battery would normally be expected to last many months or years.

NiMH batteries are particularly advantageous for high current drain applications. Alkaline batteries, which might have approximately 3000mAh capacity under low current demand (200mA) will have less than 1000mAh capacity under 1000mA (reference). Digital cameras with LCD's and flash lights can drain over 1A, quickly depleting Alkaline batteries after few shots. NiMH can handle these current levels and maintain their full capacity.

Applications that require frequent replacement of the battery, such as toys or video game controllers also benefit from use of rechargeable batteries. With the development of low self discharge NiMH's (see section above), many of occasional use applications can be replaced with NiMH rechargeables.

Lithium ion batteries are more compact than nickel metal hydride batteries.<ref>http://sg.biz.yahoo.com/070123/1/464td.html</ref>

References

<References />

See also

External links